Podzravljeni, I am interested in Kirchoff law of thermodynamics. It is mentioned in the figure below, but I do not know where all this law and what it tells me. But I must mention that I am a professor answered that this is in fact the derivation of Cp, ie the temperature of the exhaust enthalpy and there was no proper. http://shrani.si/f/0/d0/gFp9QIu/td.jpg Ahonen Posts: 53 Joined: 01/02/2014 11:42
On the first, see eg .: http://chemwiki.ucdavis.edu/Physical_Chemistry/Thermodynamics/State_Functions/Enthalpy/Kirchhoff_Law to the second example, however, .: http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/helmholtz .html It therefore applies: If this diferenciraš, you get: This symbol means infinitezimalno change, the change can be neinfinitezimalno "nadomestiš" with: At the condition is fulfilled, ie, the following applies:. The answer to your question, therefore, is that the change to a free energy equals the change in free energy in other Isothermal process: ie. at a constant temperature:. shrink Posts: 9711 Joined: 4/9/2004 17:45
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